Using the mobility closure given by Equation 2.57 the fluxes can be eliminated. The system of first order moment equations then becomes a system of second order equations in the even moments.
With the relaxation time approximation the general equation
for is of the following form:
![]() |
(2.74) |
Besides the moments which enter in the equation for
are
and
. In addition we need
for
the relaxation term. Furthermore relaxation times and mobilities
depend on
, which needs
(and
) for its calculation.
Equation 2.74 gives an infinite hierarchy of
equations. If is fixed, we get the self-consistent
electrical field
from the Poisson equation.
Then we can calculate
by solving the linear
Equation 2.74 (with
) for
.
For order
this is a nonlinear
equation due to the dependence of
on
and
via the
temperature.
In an infinite chain we then can solve linear equations
with linear operator 2.76
to get ,
, and so on. The linearity is due to the
exclusive dependence of
and
on
and
via the
temperature. We also see that the infinite hierarchy
has a solution for arbitrary chosen
.
This is a weakness of the model, the infinite
hierarchy represents an underdetermined system of
equations and is not equivalent to the full Boltzmann equation.
The infinite system
lacks a closure condition or constraint which picks out
the ``one'' solution.
In Section 3.2 we propose to apply the maximum entropy
principle for this purpose.
As the infinite hierarchy is not equivalent to the Boltzmann
equation it is reasonable to
truncate the series at a low order . We
then have to impose an
additional equation for the highest occurring moment with order
,
to get an equal number of equations and unknowns. This closure condition
is the topic of the next chapter.
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