It has been shown that the reaction-diffusion theory is not able to predict the different observed recovery characteristics following from different stress conditions. Therefore scaling and normalization routines are empirically used to characterize the recovery traces [14, 33, 82, 61].
In Fig. 4.1 the normalization routine is depicted step by step. First, the relative recovery2 after different is normalized to the last corresponding stress value. Furthermore, all relaxation times are divided by the last stress times, yielding . The normalized data now lie on top of each other and feature the same “universal” behavior. Based on [61], this universal behavior can be described by the universal relaxation function which reads
| (4.1) |
Here denotes the relaxation depending on the total stress time and the relaxation time , the total degradation observed right at , the permanent component, which only depends on the total stress time, and stands for the total amount the device is going to recover from . As such the term universality in NBTI was not a new finding in 2007, but was already reported by Denais et al., who claimed that the relative recovery follows the same pattern when plotted over the stress time [82, 61].
Unfortunately yet no generally accepted and valid theory exists for BTI, which means that the exact form of remains speculative. Empirically derived expressions have therefore been presented so far: Kakalios et al. for example used a stretched-exponential of the form to describe “relaxation in disordered systems” [83]. Other empirical “log-like” expressions are [82] or [84]. Also a generalized power-law-like expression after [61]
| (4.2) |
amongst many others [85, 17, 86, 87], can be used. Whereas equation (4.2) can be used to fit the OTF-data from [82], the first recovery point of the MSM-data, depicted in Fig. 4.2, is unknown due to the instant recovery. The first MSM point is obtained with a delay time and according to [61, 11] even a is still too slow. Thus back-extrapolation to reconstruct the “true” initial degradation has been suggested. With we get
| (4.3) |
Provided that there is a set of relaxation data with different stress times, and can be determined, as shown in Fig. 4.2 taken from [11, 61]3 . The slight deviation for is due to the existence of a non-negligible permanent component , which is additionally present here and consequently has to be considered too.