5.4 Carrier Mobility
Lead telluride attracts attention due to its extraordinarily high carrier
mobilities at low temperatures. Values of
and
have been reported for electrons and holes,
respectively at
, which reduce to
and
at room temperature [270]. The mobilities for
electrons and holes,
and
are limited by carrier scattering
within the semiconductor. The electron mobility model is based on experimental
and Monte-Carlo simulation data [271], while the hole mobility
model relies on collected measurement data.
The Monte-Carlo technique serves as a powerful link between measurement data
and models for device simulation in hierarchical device simulation
[79]. Macroscopic average quantities such as carrier
mobility and energy relaxation times are derived from the microscopic behavior
of single electrons with statistical methods. Bulk Monte-Carlo simulations
have been carried out using the Vienna Monte Carlo simulator (VMC)
[204] applying a single particle Monte Carlo technique. For the
analysis, the two lowest conduction band valleys at L and W points,
respectively are incorporated. Several relevant stochastic mechanisms are
considered, which are phonon scattering in the acoustic and optical branch,
polar optical phonon scattering, optical deformation potential scattering, L-L
intravalley scattering, and scattering by ionized impurities. The band
structure is described by a non-parabolic approximation of the valleys using
Kane's formula [77]
|
(5.41) |
Compared to widely used materials such as silicon or germanium, the material
parameters of lead telluride show higher uncertainties, especially at higher
temperatures. The influences of the according single material parameters on
the mobility are assessed and some parameters are adjusted in an iterative
process to account for available measurement data for certain doping and
temperature values. This calibrated set of models finally serves as a basis
for the extraction of bulk mobility data in order to further calibrate the
according mobility models in the device simulator MINIMOS-NT [268].
Only a few Monte-Carlo simulations are currently documented in literature for
lead telluride. The negative differential mobility at "high-field"
conditions in lead telluride has been investigated in [272] at
. This work has been extended to selected lead-tin telluride
alloys in [273]. A comprehensive investigation including both
measurements and Monte-Carlo simulation results for the hot-electron behavior
in lead telluride as well as lead-tin telluride alloys is presented in
[274]. However, all these studies are limited to a temperature of
and focus on the influence of the W-valley.
In recent work, Palankovski et al. [275] provided
results for the electron mobility as a function of temperature up to
, carrier concentration, and electric field.
In contrast to semiconductors with wider band gaps such as silicon, the
temperature dependence of several parameters becomes more pronounced. Thus,
these parameters are modeled accordingly by introducing temperature dependent
expressions. Model parameters applied in the simulations are collected in
Table 5.9.
Table 5.9:
Parameters for several scattering models incorporated in Monte-Carlo simulations.
quantity |
symbol |
value |
unit |
valley separation energy |
|
|
eV |
effective masses |
|
|
|
|
|
|
|
|
|
|
|
|
|
|
|
sound velocities |
|
|
m/s |
|
|
|
m/s |
lattice constant |
|
|
|
mass density |
|
|
kg/m
|
non-parabolicity constants |
|
|
1/eV |
|
|
|
1/eV |
relative permittivities |
|
|
|
|
|
|
|
acoustical deformation potential |
|
|
eV |
optical phonon energy |
|
|
meV |
intervalley phonon energy |
|
|
meV |
intervalley coupling constant |
|
|
eV/cm |
ODP coupling constant |
|
|
eV/cm |
|
Due to the low driving forces far below saturation effects within
thermoelectric applications, mobility model parameters are obtained for the
low-field case. Low-field mobilities for electrons and holes are modeled by
a two-stage model [268]. The temperature dependent mobilities for
intrinsic and low doped samples, where lattice scattering is the dominant
scattering mechanism, are expressed by a power law
|
(5.42) |
Figure 5.11:
Temperature dependence of the electron mobility in lead telluride
for different dopings.
|
Figure 5.12:
Doping dependent electron mobility degradation in lead telluride at
room temperature.
|
Figure 5.13:
Temperature and doping dependent hole mobility in lead telluride.
|
Doping dependent mobility degradation due to ionized impurity scattering is
introduced using a simplified Caughey-Thomas equation [276]
|
(5.43) |
where
depicts the temperature dependent mobilities for undoped samples
(5.42) and
stands for the total impurity concentration.
The mobility degradation with increasing impurity concentration is determined
by
and
. While
depicts the
impurity concentration, where the according mobility becomes
|
(5.44) |
the exponent
models the gradient of the mobility degradation with
increasing impurity concentration
|
(5.45) |
The parameters for lead telluride are collected in Table 5.10 for
electrons and holes, respectively.
Table 5.10:
Parameters for lead telluride mobility models.
|
The validity of the model for electrons is illustrated in
Figures 5.11 and 5.12. Fig. 5.11 depicts the
temperature dependent electron mobility for doping concentrations of
and
, respectively.
The temperature dependence follows a power law, where the exponent's value of
for low doped samples reduces for higher dopings. Fig. 5.12
illustrates the mobility degradation with increasing dopant concentrations at
room temperature. Ueta's data are based on epitaxial layers grown on
and are thus somewhat lower than bulk values due to additional
surface scattering and lattice mismatch. An overview of hole mobility data is
given in Fig. 5.13, where measurement data from
[270,277,194,278,279,280,281]
has been used as a basis for the hole mobility model.
M. Wagner: Simulation of Thermoelectric Devices