All useful semiconductor electronics require conductive signal paths in and out of each device
as well as conductive interconnects to carry signals between devices on the same chip and to
external circuit elements that reside off-chip. While SiC itself is theoretically capable of
operation under extreme conditions (Section 2.2), such functionality
is useless without contacts and interconnects that are also capable of operation under the
same conditions. Previously-developed conventional contact and interconnect technologies will
likely not be sufficient for reliable operation under such extreme conditions. The durability
and reliability of metal-semiconductor contacts and interconnects are one of the main factors
limiting the operational high-temperature limits of SiC electronics. Similarly, SiC high-power
device contacts and metalizations will have to withstand both high temperature and high
current density stress.
The subject of metal-semiconductor contact formation is a
very important technical field too broad to be discussed in detail here. More general
background discussions on metal-semiconductor contact physics and formation are presented
in [37,77]. These references primarily discuss ohmic contacts to
conventional narrow-bandgap semiconductors such as silicon and GaAs. Specific overviews of SiC
metal-semiconductor contact technology can be found
in [78,79,80].
The same basic physics and current transport
mechanisms that are present in narrow-bandgap contacts, such as surface states, Fermi-pinning,
thermionic emission, and tunneling, also apply to SiC contacts. A natural consequence of the
wider bandgap of SiC is the higher effective Schottky barrier height. Analogous with
narrow-bandgap ohmic contact physics, the microstructural and chemical state of the SiC-metal
interface is crucial to contact electrical properties. Therefore, pre-metal-deposition surface
preparation, metal deposition process, choice of metal, and post-deposition annealing can all
greatly impact the performance of metal-SiC contacts. Because the chemical nature of the
starting SiC surface is strongly dependent on surface polarity, it is not uncommon to obtain
significantly different results when the same contact process is applied to the silicon face
surface versus the carbon face surface.
Subsections