The popular drift-diffusion model can be derived directly from Boltzmann's transport equation
by the method of moments [104] or from the basic principles of irreversible
thermodynamics [105]. In this model the electron current density is expressed as
a sum of two components: The drift component which is driven by the electric field and the
diffusion component caused by the gradient of the electron concentration
(3.13)
where and are the mobility and the diffusivity of the electron gas,
respectively. It is clear from the above reasoning that for anisotropic materials and
are all tensors of second rank and have the same form as the representative tensor in (3.2). They are related by the Einstein relation
(3.14)
where
is the Boltzmann constant and
the lattice temperature which is constant
as the electron gas at drift diffusion is assumed to be in thermal equilibrium.
The
current relation (3.13) is inserted into the continuity (3.11)
and (3.12) to give a second order parabolic differential equation which is then
solved together with POISSON's equation (3.10). More generally, according to the
phenomenological equations of drift-diffusion the electron and hole current densities
and
can be expressed as
(3.15)
(3.16)
These current relations account for position-dependent band edge energies,
and
, and position-dependent effective masses, which are included in
the effective density of states, and . The index 0 indicates
that and are evaluated at some (arbitrary) reference temperature,
, which is constant in real space regardless of what the local
values of the lattice and carrier temperatures are.