According to FOURIER's law (e.g. to Chapter 2)
the heat flow between two regions having different temperatures is
determined by the temperature gradient and a proportional factor
.
The value of the thermal conductivity for metals is related to
the electrical conductivity because the electron gas in the metal transports the
heat as well as the electrical current.
WIEDEMANN and FRANZ found that the ratio between the electrical and
thermal conductivity for a metal is proportional to the absolute temperature
|
(3.16) |
Later on, this proportionality factor
was identified by LORENZ as
|
(3.17) |
Equation (3.16) is referred to as the WIEDEMANN-FRANZ-LORENZ law and
considers only the contribution of the heat transport capabilities of the
electrons.
Due to the different material properties, each material has its own LORENZ
number, which differs from the theoretical value and generally depends on the
temperature.
Table 3.3:
Typical values for the thermal conductivities of various materials.
Material |
[W/K] |
References |
Si Nanowires |
|
[77,78] |
Diamond |
|
[79] |
Cu |
|
[191,39] |
|
|
[191,39] |
|
|
[191,39] |
|
|
[191,39] |
Al |
|
[33] |
|
|
[33] |
|
|
[33] |
|
|
[33] |
n-polySi |
|
[192,193,194,80,195] |
p-polySi |
|
[194] |
Si |
|
[79,136] |
|
|
[79,136] |
|
|
[79,136] |
|
|
[79,136] |
Ge |
|
[79,136] |
|
|
[79,136] |
|
|
[79,136] |
|
|
[79,136] |
GaAs |
|
[79] |
|
|
[25] |
|
|
[25] |
Nevertheless, (3.17) is a very good approximation for metals at
temperatures above the DEBYE3.3 temperature
[142]. Better agreement with measurements can be obtained
using an adjusted model
|
(3.18) |
where the term
can even be of the same order of magnitude as the
WIEDEMANN-FRANZ-LORENZ term.
For temperatures below
, a second-order term might have to be
included, according to the model
|
(3.19) |
where for temperatures below the DEBYE temperature
the parameter
is often negligible.
Another approach to describe both temperature regimes is to use an empirical
polynomial model of second order
|
(3.20) |
which is a TAYLOR series for the thermal resisitivity
at the
reference temperature
. Here,
is the thermal conductivity at
the reference temperature
and the coefficients
and
are the corresponding first- and second-order temperature
coefficients.
As a first approach the thermal conductivity can be assumed to follow the
WIEDEMANN-FRANZ-LORENZ law, also for nonmetalic materials.
However, to improve the model accuracy for semiconducting and insulating
materials, a polynomial model may be used.
A comparison of typical values of the thermal conductivities of common
materials is given in Tab. 3.3 and Figure 2.9, where Tab. 3.3 shows
a list of common materials ordered by descending thermal conductivities and
Figure 2.9 gives an overview of the temperature dependence of various
materials compared to Si and Ge.
Stefan Holzer
2007-11-19